In this work,the electrochemical behaviors of SAM2X5 Fe-based amorphous alloy coating and hard chromium coating were comparatively studied in 3.5 wt％ NaC1 solution.In comparison with the hard chromium coating,the SAM2X5 coating exhibited a wider and stable passive region with lower passive current density in the potentiodynamic polarization and showed a considerably lower current density at different anodic potentials in the potentiostatic polarization.In order to understand the passivation mechanism of the Fe-based amorphous coating,the components of the passive films formed at various polarization potentials were examined by X-ray photoelectron spectroscopy.The synergistic effect of Mo,W,Mn and Cr in the passive films was systemically analyzed.It has been revealed that Mo and W facilitate the formation of compact and stable Cr2O3 passive film at lower potentials,and the substantial enrichment of Mn in the passive film enhances the passivation ability at relatively higher potentials.The deep understanding of the passivation characteristics in multicomponent alloy systems could provide a guide for the design of corrosion-resistant amorphous alloy coatings for engineering applications.