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金属簇化学是当前十分活跃的研究领域.从应用前景看可开发出具有特殊功效的新型均相催化剂.有机铁簇合物以价格低廉、资源丰富为优势,在金属簇化学中的研究尤为突出.Fe_3(CO)_(12)在羰基铁簇的合成中是一个非常有用的化合物,与Fe(CO)_5相比,配位活性更高.与许多有机硫化物(如(?)S,R’SR等)反应所得的主产物都是羰基铁的硫化物Fe_3(CO)_9S_2,
Metal cluster chemistry is currently a very active field of research.From the application prospect, we can develop a new type of homogeneous catalyst with special effects.Organium iron cluster is characterized by low cost and abundant resources, especially in the study of metal cluster chemistry .Fe_3 (CO) _ (12) is a very useful compound in the synthesis of carbonyl iron clusters and has a higher coordination activity than Fe (CO) _5. In combination with many organic sulfides such as (?) S, R’SR, etc.) are the main products of carbonyl iron sulfide Fe_3 (CO) _9S_2,