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对新型高温合金(3YC52)的抗氧化机理进行了系统研究。结果表明,研制合金(3YC52)具有的优异抗氧化性能在于高温下合金表面能形成致密保护层。扫描电镜(SEM)、电子探针显微分析(EPMA)和X射线衍射分析(XRD)分析表明,1100℃,合金氧化层的内层为Cr2O3,外层为Al2O3;1300℃,合金氧化层为单一的Al2O3。差热分析(DTA)研究表明(Al,Cr)2O3和α-Al2O3的形成分别在1060℃和1356℃达到最大值。当温度大于1150℃时,Cr2O3易剥落,因此随着时间的延长,最终留下致密的α-Al2O3保护层。
The antioxidant mechanism of the new superalloy (3YC52) was studied systematically. The results show that the developed alloy (3YC52) has the excellent oxidation resistance of the alloy surface at high temperatures to form a dense protective layer. Scanning electron microscopy (SEM), electron probe microanalysis (EPMA) and X-ray diffraction (XRD) analysis showed that the inner layer of the oxide layer is Cr2O3 and the outer layer is Al2O3 at 1100 ℃. The alloy oxide layer is Single Al2O3. Differential thermal analysis (DTA) studies show that the formation of (Al, Cr) 2O3 and α-Al2O3 reach their maximum at 1060 ° C and 1356 ° C, respectively. When the temperature is more than 1150 ℃, Cr2O3 is easy to peel off, so as time goes by, eventually leave a dense α-Al2O3 protective layer.