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Two novel mononuclear complexes with 5-chloro-8-(methoxycarbonylmethoxy)quinoline ligand(L), namely, HgLBr_2 1 and CuL_2Cl_2 2, have been prepared by solvothermal reaction of(5-chloro-quinolin-8-yloxy)acetic acid with HgBr_2 and CuCl_2, respectively. Thei