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选择性氧化烯烃分子是具有挑战性的研究课题.在众多的氧化剂分子中,分子氧吸引着化学家的目光.然而,基态的分子氧与大部分烯烃分子自旋禁阻,极大地限制着它的应用.光敏氧化反应能够有效克服这一瓶颈问题[1~4].相对于很多热化学反应,光敏氧化反应中光和氧作为纯洁试剂参与反应,
Selective oxidation of alkene molecules is a challenging research topic in which molecular oxygen attracts the attention of chemists among many oxidant molecules However, the spin-forbidding of the ground state molecular oxygen with most olefin molecules greatly limits .Photosensitive oxidation can effectively overcome this bottleneck problem.1-4 Compared with many thermochemical reactions, photooxidation and oxygen are involved in the reaction as pure reagents in the photosensitive oxidation reaction,