【摘 要】
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In this review, a recent development of cationic ?-diimine palladium(II) complexes for ethylene polymerization and copolymerization with polar functionalized co
【机 构】
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State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University,S
【出 处】
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Science China(Chemistry)
论文部分内容阅读
In this review, a recent development of cationic ?-diimine palladium(II) complexes for ethylene polymerization and copolymerization with polar functionalized comonomers was briefly described. First, the polymerization mechanism for this type of catalysts was discussed. Next, recent advances in ligand design were provided with special focus on the influence of ligand structures on the catalytic polymerization properties. Last, the ethylene homopolymerization and copolymerization with various polar comonomers, especially acrylate and vinyl ethers were summarized.
In this review, a recent development of cationic? -diimine palladium (II) complexes for ethylene polymerization and copolymerization with polar functionalized comonomers was briefly described. First, the polymerization mechanism for this type of catalysts was discussed. Next, recent advances in ligand design were provided with special focus on the influence of ligand structures on the catalytic polymerization properties. Last, the ethylene homopolymerization and copolymerization with various polar comonomers, especially acrylate and vinyl ethers were summarized.
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