【摘 要】
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Nanostructured columns with a length about several tens of micrometer and a diameter of about 80 nm were obtained by molecular recognition directed self-assemb
【出 处】
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Chemical Research in Chinese Universities
论文部分内容阅读
Nanostructured columns with a length about several tens of micrometer and a diameter of about 80 nm were obtained by molecular recognition directed self-assembly of a pair of comple- mentary molecular components, 4-amino-2 , 6-didodecylamino-1 , 3, 5-triazine(M) and 5- (4-dode- cyloxybenzylidene )-(1H, 3H)-2, 4, 6-pyrimidinetrione (B) in chloroform. In this system, with positive cooperativity, π-aromatic stacking and van der Waals interactions as well as hydrogen bonds cause the formation of the nanocolumns.
Nanostructured columns with a length of about several tens of micrometers and a diameter of about 80 nm were obtained by molecular recognition directed self-assembly of a pair of comple mentary components, 4-amino-2, 6-didodecylamino-1, 3, 5-triazine (M) and 5- (4-dode- cyloxybenzylidene) - (1H, 3H) -2,4,6- pyrimidinetrione (B) in chloroform. In this system, with positive cooperativity, der Waals interactions as well as hydrogen bonds cause the formation of the nanocolumns.
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