从构筑静电自组装聚电解质 /有机染料插层蒙脱土光致变色纳米复合膜所必需的基本纳米构件有机染料插层蒙脱土光致变色纳米复合物的设计出发 ,制备了具有光致变色功能的蒙脱土 /阳离子偶氮染料 (GTL)插层纳米复合物 .研究发现 ,插入蒙脱土层间的GTL热稳定性大幅度提高 .由于GTL在纳米受限空间的超分子有序结构共轭 ,使偶氮基团的光吸收带发生了高达 91nm的显著红移 .使用该插层纳米复合物构件与阳离子聚电解质 (PDAC)通过静电自组装得到了生长均匀、排列规整有序的光致变色聚电解质 /阳离子偶氮染料插层蒙脱土纳米复合膜 From the design of the basic nanocomposite organic dye intercalated montmorillonite photochromic nanocomposite, which is necessary for constructing the self-assembled polyelectrolyte / organic dye intercalated montmorillonite photochromic nanocomposite film, a photochromic Functionalized montmorillonite / cationic azo dye (GTL) intercalation nanocomposites.It was found that the thermal stability of GTL intercalated into montmorillonite layers increased greatly.As a result of the supramolecular ordered structure of GTL in nanometer confined spaces Conjugated, so that the azo group of the optical absorption band up to 91nm significant red shift.Using the intercalated nanocomposites and cationic polyelectrolyte (PDAC) by electrostatic self-assembly to obtain a uniform growth, orderly and orderly arrangement Photochromic polyelectrolyte / cationic azo dye intercalated montmorillonite nanocomposite film