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Gd-doped Bi2O3 visible-light-driven photocatalysts with different Gd loadings (0-4 at%) were synthesized by a simple hydrothermal method.The morphology, structural properties of the as-prepared catalysts were studied by X-ray powder diffraction, BET surface area, UV-vis absorption spectrum, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopic techniques.