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A new two-dimensional (2D) manganese(II) coordination polymer {[Mn(bidc)(H2O)2]· 2H2O}n (H2bidc = benzimidazole-5,6-dicarboxylic acid) was synthesized, and characterized by X-ray crystallography and other measurements. The complex crystallizes in the orthorhombic system, space group Pbca with a = 7.0218(7), b = 17.9701(18), c = 19.0697(19), V = 2406.3(4)3, Z = 8, Dc = 1.823 g/cm3, Mr = 330.14, F(000) = 1344, μ(MoKα) = 1.140 mm-1, S = 1.055, R = 0.0305 and wR = 0.1012 for 2130 observed reflections (I > 2σ(I)). The title complex consists of a novel 2D network with a topology of short symbol (4.82)(4.82).
A new two-dimensional (2D) manganese (II) coordination polymer was synthesized and characterized by X-ray crystallography and other measurements. The complex crystallizes in the orthorhombic system, space group Pbca with a = 7.0218 (7), b = 17.9701 (18), c = 19.0697 (19) (I> 2σ (8) Dc = 1.823 g / cm3, Mr = 330.14, F (000) = 1344, μ (MoKα) = 1.140 mm-1, S = 1.055, R = 0.0305 and wR = 0.1012 for 2130 observed reflections The title complex consists of a novel 2D network with a topology of short symbol (4.82) (4.82).