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Copper(Ⅱ)-ferron(7-iodo-8-hydroxyquinoline-5-sulfonate) one-dimensional coordination polymer Na 2 n [Cu(Ferron) 2] n ·6 n H 2O was synthesized and investigated by X-ray diffraction method. The polymer exhibits a linear structure by the bis-iodine-axial coordination to the octahedral Cu(Ⅱ) center,which is stabilized by the iodine-aromatic ring(edge and face) and iodine-iodine interactions between the polymer lines,forming a special layer structure. The complex belongs to a triclinic system,space group P 1, a =0.648 4(19) nm, b =0.654 5(19) nm, c =1.911(6) nm, α=85.42(5)°,β=85.78(5)°,γ=72.99(4)°,V =0.772(4) nm 3 and Z=1 .
Copper (Ⅱ) -ferron (7-iodo-8-hydroxyquinoline-5-sulfonate) one-dimensional coordination polymer Na 2 n [Cu (Ferron) 2] n · 6 n H 2O was synthesized and investigated by X-ray diffraction method The polymer exhibits a linear structure by the bis-iodine-axial coordination to the octahedral Cu (II) center, which is stabilized by the iodine-aromatic ring (edge and face) and iodine-iodine interactions between the polymer lines, forming a The complex belongs to a triclinic system, space group P 1, a = 0.648 4 (19) nm, b = 0.654 5 (19) nm, c = 1.911 (6) nm, α = 85.42 , β = 85.78 (5) °, γ = 72.99 (4) °, V = 0.772 (4) nm 3 and Z = 1.