合成了β-环糊精与麝香草酚的包合物1,利用X射线衍射和核磁技术分别测定了包合物在固态和溶液中的包结行为.晶体学研究表明,每个β-环糊精的空腔都包含一个麝香草酚分子,并通过大口端羟基间的氢键形成了头对头的二聚体,进而形成了通道状的多聚超分子结构.二维核磁研究表明,在水溶液中麝香草酚进入环糊精的空腔形成了主客体包合物. The inclusion complex 1 of β-cyclodextrin and thymol was synthesized and its inclusion behavior in solid solution and solution was determined by X-ray diffraction and nuclear magnetic resonance technique, respectively. Crystallographic studies showed that each β-ring The dextrin cavity contains a thymol molecule and forms a head-to-head dimer through the hydrogen bond between the macroscopic hydroxyl groups, forming a channel-like polymeric supramolecular structure. Two-dimensional nuclear magnetic studies show that in the Thymol in aqueous solution enters the cyclodextrin cavity to form a host-guest inclusion complex.