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An interesting T4(2)5(2) water tape formed by fused cyclic water pentamers and tetramer was self-assembled in a new inorganic host [Ni(L)(phen)2]·5H2O (L = L-cysteic acid) and characterized by X-ray diffraction. Each [Ni(L)(phen)2] molecule crystallizes with five water molecules with a molecular formula of [Ni(L)(phen)2]·5H2O. The T4(2)5(2) water tape and [Ni(L)(phen)2] molecules assemble into a network of water tapes sandwiched between [Ni(L)- (phen)2] tapes. The network is stabilized by π-π stacking between [Ni(L)(phen)2] molecules and three types of hydrogen-bonding interactions between [Ni(L)(phen)2] molecules, water molecules, and water and [Ni(L)(phen)2] molecules.
An interesting T4 (2) 5 (2) water tape formed by fused cyclic water pentamers and tetramer was self-assembled in a new inorganic host [Ni (L) (phen) 2] · 5H2O (L = L-cysteic acid) and Each of [Ni (L) (phen) 2] molecule crystallizes with five water molecules with a molecular formula of [Ni (L) (phen) 2] The network is stabilized by π-π stacking between [Ni (L) (phen) 2] molecules assembled into a network of water tapes sandwiched between [Ni (Phen) 2] molecules and three types of hydrogen-bonding interactions between [Ni (L) (phen) 2] molecules, water molecules, and water and [Ni (L) (phen) 2] molecules.