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A series of polymeric oxyhaloplumbates[Pb3 I2(μ4-O)L]n(1,H2L=ethylene glycol)and[Pb8 M(μ3-O)2 X8(XH)L3]n{X=Br,M=Mn(2 a),Co(2 b);X=I,M=Mn(2 c),Co(2 d)}have been synthesized under solvothermal conditions and structurally characterized.1 consists of an infin