用光电子能谱、Auger电子能谱实验和量子化学计算研究了Ni-P和Pd-Ni-P非晶态合金的电子结构。结果表明:磷的s,p电子和Ni,Pd的s,d电子成键,Fermi面处的态密度下降,能带结构明显变化。因此,用刚性能带-电荷迁移模型对Ni-P和Pd-Ni-P等非晶态合金的磁性及核磁性质所作的解释是不合乎实际情况的。 The electronic structures of Ni-P and Pd-Ni-P amorphous alloys were investigated by photoelectron spectroscopy, Auger electron spectroscopy and quantum chemistry calculations. The results show that the electron density of s and p electrons of phosphorus and s and d of Ni and Pd decrease and the density of state at Fermi surface decreases, and the band structure changes obviously. Therefore, it is unrealistic to interpret the magnetic and magnetic properties of amorphous alloys such as Ni-P and Pd-Ni-P using the rigid band-charge transfer model.