Versatile functionalization of amylopectin for effective biomedical applications

来源 :Science China(Chemistry) | 被引量 : 0次 | 上传用户:William_hui
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Successful gene vectors should be with high transfection efficiency and minimal cytotoxicity. Natural polysaccharides, due to their good biocompatibility and biodegradability, have been widely studied and applied. Amylopectin is one of polysaccharides with dendritic structure and numerous hydroxyl groups that could be used for subsequent modification. In this work, a series of dendritic cationic gene vectors comprising amylopectin backbones and poly(2-(dimethylamino) ethyl methacrylate)(PDMAEMA) side chains with different lengths(termed as AMY-PDs) were readily prepared by atom transfer radical polymerization(ATRP). The gene condensation ability, cytotoxicity and gene transfection of AMY-PDs carriers were investigated. In comparison with “gold-standard” poly(ethyleneimine)(PEI, 25 k Da), the AMY-PDs exhibited higher transfection efficiency with lower cytotoxicity. AMY-PDs could be further modified with Au nanoparticles(termed as AMY-PD@Au). The potential of the AMY-PD@Au vectors to be utilized as a CT contrast agent for imaging of cancer cells was investigated. Such AMY-PD@Au vectors may realize gene therapy with the ability of real-time imaging. Successful gene vectors should be with high transfection efficiency and minimal cytotoxicity. Due to their good biocompatibility and biodegradability, have been widely studied and applied. Amylopectin is one of polysaccharides with dendritic structure and numerous hydroxyl groups that could be used for subsequent modification . This work, a series of dendritic cationic gene vectors comprising amylopectin backbones and poly (2- (dimethylamino) ethyl methacrylate (PDMAEMA) side chains with different lengths (termed as AMY-PDs) were provided prepared by atom transfer radical polymerization ( ATRP). The gene condensation ability, cytotoxicity and gene transfection of AMY-PDs carriers were investigated. In addition, the AMY-PDs examined higher transfection efficiency (PEI, 25 kDa) with lower cytotoxicity. AMY-PDs could be further modified with Au nanoparticles (termed as AMY-PD @ Au). The potential of the AMY-PD @ Au vectors to b Such AMY-PD @ Au vectors may realize gene therapy with the ability of real-time imaging.
其他文献
目的探讨急性毒鼠强中毒血清肌酸激酶及肌钙蛋白I变化的原因和意义。方法测定48例急性毒鼠强中毒血清肌酸激酶(CK、CK-MB)及肌钙蛋白I,同时以癫痫病人和急性心肌梗死患者作对
山西省翼城县丹阳小学是一所年轻的学校,在新课堂改革形势下,如何实现既能减轻学生过重的课业负担,又能促进学生学习方式的改变;既能实现县教育局提出的高效课堂要求,还能保
首次用CFU-ALL极限稀释液体微培养法,对16例初诊,14例CR期ALL骨髓进行培养,并用8例正常,11例再生骨髓作为CFU-ALL阴性对照。结果显示:初诊B系ALL骨髓以重叠型集落伴CD(10+)细胞>20%为特点;初诊T-ALL集落也属重叠型(CD(2+)、CD(3+)、CD(7+)).而正常和再生
国内煤焦油市场商谈气氛尚可,经过前期的迅速调涨,市场涨势渐有放缓,市场观望气氛有所转浓,目前华东地区主流价格位于2200-2300元/吨,那么基于货紧支撑的拉涨行为,后市空间还
自从二次世界大战之后,世界上许多发达国家和某些发展中国家,如日、美、英,以及印度等国家都非常重视学生营养工作,实行中小学的学校“给食制度”。实践证明这一制度已经取
国际地球年~(?)地学为社会服务2007-2009 联合国第60届大会于2005年12月通过决议,将2008年定为联合国国际地球年,我国是提案国之一。该项活动是联合国成立以来第一次以地学
全球领先的汽车内饰系统供应商佛吉亚与三菱化学公司合作,开发一种100%绿色的生物基塑料,由Bio Amber公司提供生物基琥珀酸进行生产。该产品100%用天然材料合成,与普通材质相
癌胚抗原(Carcino-embryonic antigen 简称CEA)在癌症患者血清中含量特异性升高,对癌症的诊断,病情动态观察有重要的临床价值。我们应用放射免疫方法对急性白血 Carcinoemb
众所周知,说课就是教师针对某一观点、问题或具体课题,口头表述其教学设想及其理论依据。说得简单点,说课其实就是说说你是怎么教的,为什么要这样教。其内容一般包括说教材(
藏政办发[2008]124号(二○○八年十月十一日)各行署、拉萨市人民政府,自治区各委、办、厅、局:为进一步规范和管理我区地震灾害调查与评估的客观性、公正性和科学性,根据《中