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本文讨论了分子内环化对非线型缩聚反应凝胶点的影响,应用数学期望的基本概念,推导得到包含内环化校正因子的凝胶化理论,经过适当内环化校正的理论凝胶点,与实验值能较好地符合。
In this paper, the influence of intramolecular cyclization on the gel point of non-linear polycondensation reaction was discussed. The basic concept of mathematical expectation was applied and the gelation theory including inner cyclization correction factor was deduced. The theoretical gel Point, and the experimental value can better meet.