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Superconductivity was achieved in Ti-doped iron-arsenide compound Sr4Cr0.8Ti1.2O6Fe2As2 (abbreviated as Cr-FeAs-42622). The X-ray diffraction measurement shows that this material has a layered structure with the space group of P4/nmm,and with the lattice constants a = b = 3.9003 and c = 15.8376 . Clear diamagnetic signals in ac susceptibility data and zero-resistance in resistivity data were detected at about 6 K,confirming the occurrence of bulk superconductivity. Meanwhile we observed a supercon-ducting transition in the resistive data with the onset transition temperature at 29.2 K,which may be induced by the nonuniform distribution of the Cr/Ti content in the FeAs-42622 phase.
Superconductivity was achieved in Ti-doped iron-arsenide compound Sr4Cr0.8Ti1.2O6Fe2As2 (abbreviated as Cr-FeAs-42622). The X-ray diffraction measurement shows that this material has a layered structure with the space group of P4 / nmm, and with the lattice constants a = b = 3.9003 and c = 15.8376 . Clear diamagnetic signals in ac susceptibility data and zero-resistance in resistivity data were detected at about 6 K, confirming the occurrence of bulk superconductivity. Meanwhile we observed a supercon- ducting transition in the resistive data with the onset transition temperature at 29.2 K, which may be induced by the nonuniform distribution of the Cr / Ti content in the FeAs-42622 phase.