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Three complexes, [Pr(NO_3)_3(HL)_2] (1), [Nd(NO_3)_3(HL)_2] (2) and [Er(NO_3)_3(HL)_2]·0.5H_2O (3), were synthesized from the reaction of a Schiff base ligand 2-[(4-methylphenylimino)methyl]-6-methoxyphenol (C_ 15H_ 15NO_2, HL) with Ln(NO_3)_3·6H_2O (Ln=Pr, Nd, Er). Characterization by single-crystal X-ray diffraction technique, elemental analysis, molar conductance, FT-IR, UV-Vis, 1H NMR and thermal analysis shows the title complexes are neutral molecules where the central Ln(Ⅲ) ion is ten-coordinated in biapical anti-hexahedron prism geometry, with four oxygen atoms of the phenolic hydroxy and methoxy groups in the two bidentate Schiff base ligands and six oxygen atoms provided by the three bidentate NO_3- anions. Additionally, the kinetic mechanism of thermal decomposition of complex 3 was determined with a TG-DTG curves by both integral and differential methods. The functions of thermal decomposition reaction mechanism and the equation of kinetic compensation effect were obtained.
Three complexes, [Pr (NO_3) _3 (HL) _2] (1), [Nd (NO_3) _3 (HL) _2] and [Er (NO_3) _3 (HL) _2] , were synthesized from the reaction of a Schiff base ligand 2 - [(4-methylphenylimino) methyl] -6-methoxyphenol (C_15H_15NO_2, HL) with Ln (NO_3) _3 · 6H_2O (Ln = Pr, Nd, Er). Characterization by single-crystal X-ray diffraction technique, elemental analysis, molar conductance, FT-IR, UV-Vis, 1H NMR and thermal analysis shows the title complexes are neutral molecules where the central Ln (III) ion is ten-coordinated in biapical anti-hexahedron prism geometry, with four oxygen atoms of the phenolic hydroxy and methoxy groups in the two bidentate Schiff base ligands and six oxygen atoms provided by the three bidentate NO_3-anions. Additionally, the kinetic mechanism of thermal decomposition of complex 3 was determined with a TG-DTG curves by both integral and differential methods. The functions of thermal decomposition reaction mechanism and the equation of kinetic compensation effect were were able were obtained ed.