论文部分内容阅读
报道了 3个取代多联吡啶配体 [4-苯基 -2 ,2′∶ 6′,2″-三联吡啶 ( L1) ,4′,4″-二苯基 -2 ,2′∶ 6′,2″∶ 6″,2 -四联吡啶 ( L2 )和 4′,4 -二苯基 -2 ,2′∶ 6′,2″∶ 6″,2 ∶ 6 ,2″″-五联吡啶 ( L3 ) ]的 4个过渡金属配合物[Co( ) ( L 1) 2 ] ( Cl O4) 2 ( CH3 CN) ( 1) ,[Co( ) ( L 2 ) ( Ac O) ( H2 O) ] ( Cl O4) ( 2 ) ,[Mn( ) ( Ac O) ( L 2 ) ( H2 O) ] .( Cl O4) ( 3 ) ,[Co( ) ( L 3 ) ( CH3 CN) ] ( Cl O4) 2 ( 4 ) ]的合成及其晶体结构 .结构分析表明 ,金属离子对配合物的形成有诱导作用 .
Three substituted polypyridyl ligands [4-phenyl-2, 2 ’: 6’, 2 “-terpyridine (L1), 4 ’, 4” 2 “: 6”, 2 “: 6”, 2 "- dipyridyl (L2) and 4 ’ (Co2) (ClO4) 2 (CH3CN) (1), [Co () (L2) (AcO) (H2O)) of the four transition metal complexes [Co (ClO4) (2), [Mn () (AcO) (L2) (H2O)]. O4) 2 (4)] and its crystal structure.The structural analysis showed that the metal ions induced the formation of the complex.