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各类型醛 ,在 2 8%氨水中与 1.1当量的碘在室温下反应 5~ 6 0 min,生成相应的腈 ,除 1例因挥发性高收率为 5 7%外 ,其余 13例收率 83%~ 97%。醛在氨水中用碘直接转化为腈@赵立志
Various aldehydes were reacted with 1.1 equivalents of iodine in 28% aqueous ammonia at room temperature for 5-60 min to yield the corresponding nitrile. Except for 1 case with high volatile yield of 57%, the remaining 13 83% ~ 97%. Aldehydes in ammonia with iodine directly converted to nitrile @ Zhao Lizhi