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以Ce(NO_3)_3为催化剂、H_2O_2为氧化剂的苄醇氧化反应,在以乙酸、三氯乙酸等有机酸作溶剂条件下,可构成催化循环,实现苄醇控制氧化制备苯甲醛。同时,还研究了温度和催化剂、乙酸、H_2O_2浓度等因素对反应的影响。
Catalytic oxidation of benzyl alcohol by the oxidation of benzyl alcohol to benzaldehyde can be achieved by the oxidation of benzyl alcohol using Ce (NO_3) _3 as the catalyst and H_2O_2 as the oxidant in the presence of organic acids such as acetic acid and trichloroacetic acid. At the same time, the effects of temperature and catalyst, acetic acid and H 2 O 2 concentration on the reaction were also studied.