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应用强场近似拟合了10个假四面体Co(Ⅱ)(C_(2γ))配合物的配体独场光谱,由拟合得到的单电子矩阵元得到了各个配体的AOM参量。结果说明各配体的AOM参量同该配体与金属离子之间的配键强度相关。
The strong field approximations were fitted to the ligands’ unique spectra of 10 pseudo-tetrahedra Co (Ⅱ) (C 2γ) complexes. The AOM parameters of each ligand were obtained from the fitted single-electron matrix elements. The results show that the AOM parameters for each ligand are related to the bond strength between the ligand and the metal ion.