以 N,N -双 (3 -氨基 -2 ,2 -二甲基丙基 )草酰胺根阴离子 (Me2 oxpn)为桥联配体 ,分别端接 N,N,N ,N -四甲基乙二胺 (tmen)和 2 ,9-二甲基 -1 ,1 0 -邻菲罗啉 (Me2 -phen) ;合成和表征了 3种新的异双核配合物[Cu(Me2 oxpn) Fe(tmen) 2 ]SO4(a) ,[Cu(Me2 oxpn) Zn(tmen) 2 ]SO4(b)和 [Cu(Me2 oxpn) Zn(Me2 -phen) 2 ]SO4(c) .经元素分析、红外光谱、电子光谱、电导及磁性测量等方法推定了这些配合物的结构 .测定并研究了 (a)的变温磁化率 (4～ 3 0 0 K) ,求得交换参数 J=-1 2 .96cm-1,表明双核配合物中 Cu( ) -Fe( )离子间存在反铁磁超交换作用 .测试了 3个双核配合物的杀菌作用 N, N, N, N - Tetramethylethylenediamine (N, N, N, N - dimethylthio) oxalate was used as the bridging ligand. Three new heterodinuclear complexes [Cu (Me2 oxpn) Fe (tmen) and 2,9-dimethyl-1,10-phenanthroline (Me2-phen) were synthesized and characterized. ) 2] SO4 (a), [Cu (Me2 oxpn) Zn (tmen) 2] SO4 (b) and [Cu (Me2 oxpn) Zn (Me2 -phen) 2] SO4 , Electronic spectra, conductivity and magnetic measurements were used to estimate the structures of these complexes.The temperature-dependent susceptibility (4 ~ 300 K) of (a) was measured and studied, and the exchange parameter J = -1.2.96cm- 1, indicating the existence of antiferromagnetic super-exchange between Cu () -Fe (superscript +) in the binuclear complex.We tested the bactericidal effect of the three binuclear complexes