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A novel inorganic-organic compound (C4N2H12)(C2N2H10)2[Mo5P2O23] (1) has been synthesized by the reaction of (NH4)2MoO4, H3PO4, C2N2H8 (ethylenediaminium), C4N2H10·6H2O (piperazine hexahydrate) and water in aqueous solution under mild hydrothermal conditions. Single-crystal X-ray analysis reveals that the title compound is crystallized in the triclinic system, space group P1 with a = 9.258(19), b = 9.382(19), c = 17.681(4), α = 76.28(3), β = 84.48(3), γ = 70.82(3)o, V = 1408.9(6)3, Mr = 1122.04, Z = 2, Dc = 2.645 g/cm3, μ = 2.384 mm-1, F(000) = 1092.0, the final R = 0.0391, wR = 0.1185 and S = 1.006 for 6169 observed reflections with I > 2σ(I). The crystal packing is stabilized by intra- and intermolecular N-H···O hydrogen bonds to form an infinite 3D network.
A novel inorganic-organic compound (C4N2H12) (C2N2H10) 2 [Mo5P2O23] (1) has been synthesized by the reaction of (NH4) 2Mo04, H3PO4, C2N2H8 (ethylenediaminium), C4N2H10.6H2O (piperazine hexahydrate) and water in aqueous solution Under-mild X-ray analysis reveals that the title compound is crystallized in the triclinic system, space group P1 with a = 9.258 (19), b = 9.382 (19), c = 17.681 α = 76.28 (3), β = 84.48 (3), γ = 70.82 (3) o, V = 1408.9 (6) 3, Mr = 1122.04, Z = 2, Dc = 2.645 g / cm3, μ = -1, F (000) = 1092.0, the final R = 0.0391, wR = 0.1185 and S = 1.006 for 6169 at refs with I> 2σ (I). The crystal packing is stabilized by intra- and intermolecular NH ··· O hydrogen bonds to form an infinite 3D network.