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本文报道了4-甲基-4-苯基-2,5-环己二烯酮(A)的固相光化学反应,得到与液相光化学反应不同的重排产物A_1和A_2。A_1的结构已确证为3-甲基-2-苯基酚,A_2为2-甲基-3-苯基酚。对A的固相光化学反应机理还进行了初步探讨。
In this paper, the solid-state photochemical reaction of 4-methyl-4-phenyl-2,5-cyclohexadienone (A) was reported and the rearranged products A_1 and A_2 were obtained. The structure of A_1 has been confirmed as 3-methyl-2-phenylphenol and A_2 as 2-methyl-3-phenylphenol. A solid-phase photochemical reaction mechanism has also been initially explored.