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基于超痕量钒(Ⅴ)对(NH4)2S2O8氧化苯羟乙酸反应强烈催化作用,氧化产物苯甲醛于-0.94V(vs.SCE)处产生一灵敏的单扫描示波极谱波,表面活性剂OP具有增敏作用。据此建立钒的催化示波极谱分析新方法,线性范围20~8000/10(12)g/mL,检测限为8×10(-12)g/mL,用于铝合金分析,获得满意结果。
Based on the strong catalysis of ultra trace trace vanadium (Ⅴ) on the (NH4) 2S2O8 oxybenzene acid reaction, the benzaldehyde oxidation product produced a sensitive single-sweep oscillopolarographic wave at -0.94V (vs.SCE) Active agent OP has a sensitizing effect. Based on this, a new method for catalytic oscillopolarographic analysis of vanadium was established, with a linear range of 20 ~ 8000/10 (12) g / mL and a detection limit of 8 × 10 (-12) g / mL for aluminum alloy analysis result.