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多卤代烃在有机反应机理和结构研究中有着重要意义,作为一个有用的合成中间体,其制备也受到人们重视。我们在此报道二氯亚甲基环已烷(1)与氯及溴的反应和其它有关反应的实验结果。 1 于氯作用,主要得到加成产物1—氯—1—
Polyhalogenated hydrocarbons are of great significance in the study of the mechanism and structure of organic reactions. As a useful synthetic intermediate, their preparation has also drawn great attention. We report here the results of the reaction of dichloromethylenecyclohexane (1) with chlorine and bromine and other related reactions. 1 in the role of chlorine, the main addition product 1-chloro-1-