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The detailed surface reaction mechanism of methane on rhodium catalyst was analyzed.Comparisons betweennumerical simulation and experiments showed a basic agreement.The combustion process of homogeneouscharge compression ignition(HCCI)engine whose piston surface has been coated with catalyst(rhodium andplatinum)was numerically investigated.A multi-dimensional model with detailed chemical kinetics was built.The effects of catalytic combustion on the ignition timing,the temperature and CO concentration fields,and HC,CO and NO_x emissions of the HCCI engine were discussed.The results showed the ignition timing of the HCCIengine was advanced and the emissions of HC and CO were decreased by the catalysis.
The detailed surface reaction mechanism of methane on rhodium catalyst was analyzed. Comparisons betweennumerical simulation and experiments showed a basic agreement. Combustion process of homogeneouscharge compression ignition (HCCI) engine whose piston surface has been coated with catalyst (rhodium and platinum) was numerically investigated. A multi-dimensional model with detailed chemical kinetics was built. The results of catalytic combustion on the ignition timing, the temperature and CO concentration fields, and HC, CO and NO x emissions of the HCCI engine were discussed. The results showed the ignition timing of the HCCIengine was advanced and the emissions of HC and CO were decreased by the catalysis.