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合成了钼硅稀土二电子、四电子杂多蓝LnH3〔SiMoVI10MoV2O40〕·12H2O和LnH5〔SiMoVI8MoV4O40〕·13H2O,其中Ln=La,Ce,Pr,Nd,Sm,Gd,通过IR,UV,TG-DTA,XPS,ESR磁化率等对杂多蓝进行了表征.结果表明,杂多酸盐还原为杂多蓝后,结构上发生了轻微的畸变.
Ln = La, Ce, Pr, Nd, Sm and Gd were synthesized by IR, UV, TG-DTA , XPS, ESR magnetic susceptibility and so on heteropoly blue. The results showed that after the reduction of heteropoly acid salt to heteropoly blue, the structure of a slight distortion occurred.