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本文考价HCl从H_2O到DMSO(20wt%)-EtOH-H_2O中的迁移热力学性质,分析讨论了离子的溶剂化作用、溶质-溶剂相互作用及溶液的微观结构,并应用修正的Born方程对实验结果进行了解释。本文的工作为DMSO在临床试验及工业生产中的广泛应用提供了重要的参考数据和信息。
In this paper, the thermodynamic properties of HCl migration from H_2O to DMSO (20wt%) - EtOH-H_2O were investigated. The solvation, solute-solvent interaction and solution microstructure of the ions were analyzed and discussed. The modified Born equation The result is explained. The work in this paper provides important reference data and information for the extensive application of DMSO in clinical trials and industrial production.