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The title compound,[Zn2(H2C4BIm)(ox)2]·2H2O(1,H2C4BIm = 2,2’-(1,4-bu-tanediyl)bis(1H-benzimidazole),has been synthesized by the hydrothermal reaction of Zn(NO3)2·6H2O with H2C4BIm and Na2C2O4 in water solution.It crystallizes in the triclinic system,space group P1 with a = 9.445(9),b = 9.598(9),c = 14.962(14) ,α = 72.160(10),β = 79.905(12),γ = 83.680(11)°,Mr = 633.18,V = 1269(2) 3,Z = 2,Dc = 1.657 g/cm3,F(000) = 644,μ = 1.953 mm-1,the final R = 0.0671 and wR = 0.1689.X-ray crystal structure analysis revealed that 1 is a 3D network with(203)2(20)3 topology in which the ZnII atom can be considered as a 3-connected node and both ox2-and H2C4BIm serve as the linear linkers.
The title compound, [Zn2 (H2C4BIm) (ox) 2] .2H2 O (1, H2C4BIm = 2,2’-1,4-bu- tanediyl) bis (1H-benzimidazole), has been synthesized by the hydrothermal reaction of Zn (NO3) 2.6H2O with H2C4BIm and Na2C2O4 in water solution. It crystallizes in the triclinic system, space group P1 with a = 9.445 (9), b = 9.598 (9), c = 14.962 72.160, β = 79.905 (12), γ = 83.680 (11) °, Mr = 633.18, V = 1269 (2) 3, Z = 2, Dc = 1.657 g / cm3, F , the final R = 0.0671 and wR = 0.1689. X-ray crystal structure analysis revealed that 1 is a 3D network with (203) 2 (20) 3 topology in which the ZnII atom can be considered as a 3-connected node and both ox2-and H2C4BIm serve as the linear linkers.