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在ＨＣｌ￣（－）六次甲基四胺介质（ｐＨ４．６２）中，铜（铅）－Ｆｅｒｒｏｎ氯化四苯胂络合物产生灵敏的络合吸附波。峰电位分别为－１．４１Ｖ和－０．５７Ｖ（Ｕｓ．ＳＣＥ）。峰电流与铜、铅浓度分别在０．０００４～０．４μｇ／ｍＬ和０．００２～０．８μｇ／ｍＬ之间呈线性关系，检出限分别为０．０００２μｇ／ｍＬＣｕ和０．００１μｇ／ｍＬＰｂ。研究了极谱波的性质和电极反应机理。用拟定的方法连续测定水样和食品中的铜、铅，结果满意。
Copper (lead) -Ferron tetraphenylarsenium complex in HCl ~ (-) hexamethylenetetramine (pH4.62) yields a sensitive complex adsorption wave. The peak potentials were -1.41V and -0.57V (Us.SCE) respectively. The peak current was linear with the concentration of copper and lead in the range of 0.0004 ~ 0.4μg / mL and 0.002 ~ 0.8μg / mL with the detection limits of 0.0002μg / mL and 0.001μg / mL respectively . The polarographic wave properties and electrode reaction mechanism were studied. With the proposed method for continuous determination of copper and lead in water samples and food, the results were satisfactory.