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从二茂铁和二氯二茂钛发现以来。对其衍生物的研究极为广泛,但是钛铁双金属有机衍生物的报导极少。本文合成了一种新的二茂佚衍生物和六种钛铁双金属有机衍生物,即:3—羧基双环[2,2,1]庚—5—烯—2—甲酰基二茂铁(I),3—(1—二茂铁甲酰基)双环[2,2,1]庚—5—烯—2—甲酰氧基—氯二茂钛(Ⅱ),1—二茂铁甲酰氧基—氯二茂钛(Ⅲ),二—(1—二茂铁甲酰氧基)二茂钛(Ⅳ),1—二茂铁甲酰丙酰氧基—氯二茂钛(Ⅴ),二(1—二茂铁甲酰丙酰氧基)二茂钛(Ⅵ),1,1′—二茂铁基二甲酰丙酰氧基二茂钛(Ⅷ)。
Since the discovery of ferrocene and dichloro titanocene. The research on its derivatives is very extensive, but there are few reports on the biomimetic organotitanium derivatives. In this paper, a new diaryloxene derivative and six kinds of titanium iron bimetallic organic derivatives were synthesized, namely: 3-carboxybicyclo [2.2.1] hept-5-ene-2-formylferrocene I), 3- (1-ferroceneyl) bicyclo [2,2,1] hept-5-ene-2-carboxamido-titanocene chloride (IV), 1-ferrocenecarboxypropionyl-titanocene chloride (Ⅴ), bis (1-ferrocenecarboxyl) titanocene - ferrocenzoylpropionyloxy) titanocene (Ⅵ), 1,1’-ferrocenyldimethylpropionyloxytitanium titanate (Ⅷ).