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The key intermediate (2S, 3R)-2-citronellyl-6-methylene-heptan-2,3,7-triol (8) ofanalogues of zoapatanol was synthesized in seven steps from the chiral synthon 2. The absoluteconfiguration of the new chiral centre in compounds 5a-8 was identified as S by Mukaiyama’s method.
The key intermediate (2S, 3R) -2-citronellyl-6-methylene-heptan-2,3,7-triol (8) of analogues of zoapatanol was synthesized in seven steps from the chiral synthon 2. The absolute configuration of the new chiral center in compounds 5a-8 was identified as S by Mukaiyama’s method.