Effect of Strontium Addition to Platinum Catalyst for Propane Dehydrogenation

来源 :China Petroleum Processing & Petrochemical Technology | 被引量 : 0次 | 上传用户:alexhome
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PtSnSr/HZSM-5 catalysts with different amounts of strontium were prepared by sequential impregnation method,and characterized by BET analysis,TEM,NH3-TPD,H2-TPR,TPO and TG techniques.The results showed that the addition of strontium could modify the characteristics and properties of both acid function and metal function of Pt-Sn-based catalysts.In this case,PtSnSr/HZSM-5 catalyst with an appropriate amount of Sr(1.2%) showed higher catalytic activity and lower amount of coke deposits than PtSn/HZSM-5 catalyst.However,excessive loading of Sr could facilitate the reduction of Sn,which was unfavorable to the reaction.Afterwards,1.0 m% of Na was added into the PtSnSr(1.2%)/HZSM-5 catalyst to improve the catalytic performance in propane dehydrogenation,and this catalyst displayed the best catalytic performance during our experiments.After having been subjected to reaction for 5h,the PtSnNa(1.0%)Sr(1.2%)/HZSM-5 catalyst had achieved a higher than 95% selectivity towards propene along with a corresponding propane conversion rate of 32.2%. PtSnSr / HZSM-5 catalysts with different amounts of strontium were prepared by sequential impregnation method, and characterized by BET analysis, TEM, NH3-TPD, H2-TPR, TPO and TG techniques. The results showed that the addition of strontium could modify the characteristics and properties of both acid function and metal function of Pt-Sn-based catalysts. In this case, PtSnSr / HZSM-5 catalyst with an appropriate amount of Sr (1.2%) showed higher catalytic activity and lower amount of coke deposits than PtSn / HZSM-5 catalyst. Still, excessive loading of Sr could facilitate the reduction of Sn, which was unfavorable to the reaction. Afterwards, 1.0 m% of Na was added into the PtSnSr (1.2%) / HZSM- catalytic performance in propane dehydrogenation, and this catalyst displayed the best catalytic performance during our experiments. After the reaction to 5h, the PtSnNa (1.0%) Sr (1.2%) / HZSM- 1.Select towards propene along with a corresponding propane conversion rate of 32.2%.
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