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Micro/nanostructured crystals with controlled architectures are desirable for many applications in optics, electronics,biology,medicine,and energy conversions.Low-temperature,aqueous chemical routes have been widely investigated for the synthesis of particles,and arrays of oriented nanorods and nanotubes.In this paper,based on the ideal crystal shapes predicted by the chemical bonding theory,we have developed some potential chemical strategies to tune the microstructure of functional materials,ZnS and Nb_2O_5 nanotube arrays,MgO wiskers and nestlike spheres,and cubic phase Cu_2O microcrystals were synthesized here to elucidate these strategies.We describe their controlled crystallization processes and illustrate the detailed key factors controlling their growth by examining various reaction parameters.Current results demonstrate that our designed chemical strategies for tuning microstructure of functional materials are applicable to several technologically important materials,and therefore may be used as a versatile and effective route to the controllable synthesis of other inorganic functional materials.
Micro / nanostructured crystals with controlled architectures are desirable for many applications in optics, electronics, biology, medicine, and energy conversions. Low-temperature, aqueous chemical routes have been widely investigated for the synthesis of particles, and arrays of oriented nanorods and nanotubes. In this paper, based on the ideal crystal shapes predicted by the chemical bonding theory, we have developed some potential chemical strategies to tune the microstructure of functional materials, ZnS and Nb 2 O 5 nanotube arrays, MgO wiskers and nestlike spheres, and cubic phase Cu 2 O microcrystals were synthesized here to elucidate these strategies. We describe their controlled crystallization strategies and illustrate the detailed key factors controlling their growth by examining various reaction parameters. Current results demonstrate that our designed chemical strategies for tuning microstructure of functional materials are applicable to several technologically important materials, and there fore may be used as a versatile and effective route to the controllable synthesis of other inorganic functional materials.