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Deoxybaccatin VI (4,7,9,10,13-penta-acetoxy-2-benzoyloxy-5,20-epoxytax-11-ene) was isolated from the roots of Taxus chinensis, Rehd. var. mairei. The structural assignments of the compound were based on their spectral data, including 2D NMR experiments and chemical correlation. The X-ray crystallographic analysis of 1-deoxybaccatin VI provided unambiguous characterization for the structures. In the structure, the six-membered A ring exhibits boat conformation, the eight-membered B ring adopts boat-chair conformation, and the six-membered C ring exhibits a sofa conformation.
Deoxybaccatin VI (4,7,9,10,13-penta-acetoxy-2-benzoyloxy-5,20-epoxytax-11-ene) was isolated from the roots of Taxus chinensis, Rehd. Var. Mairei. The structural assignments of the compound were based on their spectral data, including 2D NMR experiments and chemical correlation. The X-ray crystallographic analysis of 1-deoxybaccatin VI provided unambiguous characterization for the structures. In the structure, the six-membered A ring exhibits boat conformation, the eight-membered B ring chair boat-chair conformation, and the six-membered C ring exhibits a sofa conformation.