【摘 要】
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In this study, the effect of reduced graphene oxide (rGO) on interconnected Co3O4 nanosheets and the improved supercapacitive behaviors is reported. By opti-miz
【机 构】
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Key Laboratory of Special Function Materials and Structure Design of the Ministry of Education, Key
论文部分内容阅读
In this study, the effect of reduced graphene oxide (rGO) on interconnected Co3O4 nanosheets and the improved supercapacitive behaviors is reported. By opti-mizing the experimental parameters, we achieved a specific capacitance of ~1016.4 F g-1 for the Co3O4/rGO/NF (nickel foam) system at a current density of 1 A g-1. How-ever, the Co3O4/NF structure without rGO only delivers a specific capacitance of ~520.0 F g-1 at the same current density. The stability test demonstrates that Co3O4/rGO/NF retains~95.5%of the initial capacitance value even after 3000 charge–discharge cycles at a high current density of 7 A g-1. Further investigation reveals that capacitance improvement for the Co3O4/rGO/NF structure is mainly because of a higher specific surface area (~87.8 m2 g-1) and a more optimal mesoporous size (4–15 nm) compared to the corresponding values of 67.1 m2 g-1 and 6–25 nm, respectively, for the Co3O4/NF structure. rGO and the thin-ner Co3O4 nanosheets benefit from the strain relaxation during the charge and discharge processes, improving the cycling stability of Co3O4/rGO/NF.
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