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The catalytic performances of four HRh(CO)(PPh3)3-diphosphine (BISBI, BDPX,BDNA and BINAP) systems in 1-dodecene hydroformylation were investigated and comparedwith HRh(CO)(PPh3)3-PPh3 system. The catalyst system HRh(CO)(PPh3)3- BISBI exhibited veryhigh r