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The complex[Zn_(4.5)(SSA)_3(CuL)_3(H_2O)_6]_n was synthesized and structurally determined,where SSA is fully deprotonated 5-sulfosalicylic acid(CuL,H_2L=2,3-dioxo-5,6,14,15-dibenzo-1,4,8,12-tetraazacyclo-pentadeca- 7,13-dien).The title complex crystallized in the triclinic system with space group P1,a=1.19788(17) nm,b=1.4253(2) nm,c=2.2890(4) nm,α=90.211(2)°,β=93.076(2)°,γ=90.600(2)°.The complex displayed a 1D ladderlike chain.All these 1D chains were further interlinked via hydrogen bonds,resulting in a 2D architecture.The luminescent property of the compound was also discussed.
The complex [Zn_ (4.5) (SSA) _3 (CuL) _3 (H_2O) _6] _n was synthesized and structurally determined, where SSA is fully deprotonated 5-sulfosalicylic acid (CuL, H_2L = 2,3-dioxo-5,6 , 14,15-dibenzo-1,4,8,12-tetraazacyclo-pentadeca-7,13-dien). The title complex crystallized in the triclinic system with space group P1, a = 1.19788 (17) nm, b = 1.4253 (2) nm, c = 2.2890 (4) nm, α = 90.211 (2) °, β = 93.076 (2) ° and γ = 90.600 (2) °. The complex displayed a 1D ladderlike chain.All these 1D chains were further interlinked via hydrogen bonds, resulting in a 2D architecture. luminescent property of the compound was also discussed.