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在乙醇和水的混合溶剂中,以碱式碳酸铜、邻菲口罗啉和高氯酸为原料合成了标题配合物[Cu(phen)3].(ClO4)2。该配合物晶体属单斜晶系,空间群C2/c,晶胞参数:a=3.629 56 nm,b=1.582 15 nm,c=1.223 70 nm;β=101.936°,V=6.875 17(6)nm3,Dc=1.507 g/cm3,Z=4,F(000)=2 720.0。最终偏离因子R1=0.045 2,wR2=0.067 6。晶体结构测试表明:晶体中每个铜原子与3个邻菲口罗啉的6个N原子配位,形成六配位的变形八面体。结合晶体结构进行了电化学性质研究。
The title complex [Cu (phen) 3] (ClO4) 2 was synthesized from basic cupric carbonate, phenanthroline and perchloric acid in a mixed solvent of ethanol and water. The complex crystal belongs to the monoclinic system with space group C2 / c. The unit cell parameters are: a = 3.629 56 nm, b = 1.582 15 nm, c = 1.223 70 nm; β = 101.936 °, V = nm3, Dc = 1.507 g / cm3, Z = 4, F (000) = 2 720.0. The final deviation factor R1 = 0.045 2, wR2 = 0.067 6. The crystal structure tests show that each copper atom in the crystal coordinates with six N atoms of three o-phenanthroline to form six-coordinated deformed octahedron. Combined with the crystal structure of the electrochemical properties.