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用０．５～１．０ｍｏｌ／ＬＨ２ＳＯ４溶液处理ＺｒＯ２含量为３％～５０％（摩尔分数）的锆硅复合氧化物，制得ＳＯ４２－／ＺｒＯ２－ＳｉＯ２催化剂．考察了催化剂对乙酸／丁醇酯化反应的催化作用及其制备条件（如：Ｚｒ／Ｓｉ比、沉淀剂、预焙烧温度、焙烧温度等）对催化剂性能的影响．实验结果表明，对于给定的反应，使用ＺｒＯ２含量约为１０％的ＳＯ４２－／ＺｒＯ２－ＳｉＯ２催化剂时，乙酸的转化率高于９８％；而在相同条件下使用ＳＯ４２－／ＺｒＯ２催化剂时，乙酸转化率仅４９．７％．制备条件（特别是沉淀剂）对催化剂的活性有较大的影响．
SO42- / ZrO2-SiO2 catalyst was prepared by treating zirconium-silicon composite oxide with ZrO2 content of 3% -50% (molar fraction) with 0.5-1.0mol / LH2SO4 solution. The effects of catalysts on the esterification of acetic acid / butanol and the preparation conditions (such as Zr / Si ratio, precipitant, prebaking temperature and calcination temperature) were investigated. The experimental results show that for a given reaction, the conversion of acetic acid is higher than 98% when the SO42- / ZrO2-SiO2 catalyst with a ZrO2 content of about 10% is used. However, when the SO42- / ZrO2 catalyst is used under the same conditions, the acetic acid Conversion rate is only 49.7%. Preparation conditions (especially precipitants) have a greater impact on the activity of the catalyst.