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N-Heterocyclic carbenes(NHCs)have played significant roles as a versatile class of ligands in organic catalysis,deliveri......
Coordination compounds of lanthanide trichloroacetates with 1,10-phenanthroline weresynthesized and characterized as Ln......
Synthesis and Properties of Rare Earth Complexes with 3-Ferrocenyl-5-Phenyl-Pyrazoline-1-Dithiocarba
Sodium 3-ferrocenyl-5-phenyl-pyrazoline-1-dithiocarbamate (FPPD) reacts with anhydrousrare earth chlorides in absolute ......
The complexes of 3-methoxy-2-nitrobenzoates of Pr(III), Nd(III), Sm(III), Eu(III), Gd(III), Tb(III), Er(III) and Tm(III)......
A DFT INVESTIGATION OF THE MECHANISM FOR ALTERNATINGCOPOLYMERIZATION OF STYRENE WITH CARBON MONOXIDE
Density functional theory has been employed to study the homogeneous catalytic copolymerization of styrene with carbon m......
Crystal structures and thermal decomposition kinetics of lanthanide complexes with 3,4,5-trimethoxyb
A series of lanthanide complexes with the 3,4,5-trimethoxybenzoic acid(3,4,5-tmoba) and 1,10-phenanthroline(phen),[Ln(3,......
A new asymmetric bidentate copper(Ⅱ) complex,CuL 2(HL=2-((E)-(4-bromophenylimino)methyl)-6-bromo-4-chlorophenol),has be......
Synthesis and Crystal Structure of a New Mn(Ⅱ) Coordination Polymer Based on Asymmetric Semi-rigid V
A novel manganese(Ⅱ) coordination polymer with 2-(4-carboxyphenoxy) benzoic acid (2,4’-H2oba) and 1,10-phenanthroline ......
A Novel Copper(II) Coordination Polymer with Figure-of-eight-shaped Channels Occupied by Flexible Mo
A copper(II) coordination polymer, [Cu3(HOA)2(bpp)4]n (1, H4OA = 3,3′,4,4′-oxidiphthalic acid, bpp = 1,3-bis(4-pyridyl......
Synthesis, Structure and Physical Properties of a Barium(II) Complex with 5-Sulfoisophthalic Acid So
An alkaline earth metal-organic framework [Ba(Hsip)(H2O)4]n (1, NaH2sip = 5-sulfoisophthalic acid sodium) has been const......
A new mono-nuclear Mn(Ⅱ) complex [Mn(MPT)2(NCS)(HOCH3)]ClO4(MPT = 2-methoxyl-1,10-phenanthroline) has been synthesized ......
Synthesis, crystal structure and properties of a samarium nitrate complex with 2-idobenzoic acid and
A complex [Sm(2-IBA)2(2,2’-bipy)(NO3)]2 (2-HIBA=2-idobenzoic acid; 2,2’-bipy=2,2’-bipyridine) was synthesized by solv......
First-principles characterization of formate and carboxyl adsorption on stoichiometric CeO_2(111)and
Molecular adsorption of formate and carboxyl on stoichiometric CeO_2(111) and CeO_2(110) surfaces was studied using peri......
Synthesis, Structure and Photoluminescent Property of a New 3D Cd(Ⅱ) Coordination Polymer with Terph
A new 3D Cd(Ⅱ) coordination polymer, [Cd2L(phen)(H2O)]n (1, H4 L=terphenyl-2,2 ’,4,4’-tetracarboxylic acid, phen=1,10......
Understanding of the bonding nature of uranyl and various ligands is the key for designing robust sequestering agents fo......
A new O,O’-bis(4-tert-butylphenyl)dithiophosphate complex Ni[SSP(OC6H4But- p)2]2 (1) was synthesized and characterized ......
Synthesis, Structure and Thermochromic Properties of a Copper(Ⅱ) Complex Based on Naphthyl Carboxyla
One novel copper(Ⅱ) complex, [Cu(NAA)2(bim)2]·H2O (1, HNAA = a-naphthylacetic acid, bim = benzimidazole) has been synt......
使用2-溴-1,4-对苯二甲酸和2-氨基-1,4-对苯二甲酸为配体,在溶剂热条件下得到了两个结构新颖的化合物Cd(BrBDC)(py)(1)和Cd(NH2BDC......
Two new Cu(II) complexes have been synthesized with two different bidentate N_2O_2 donor Schiff base ligands HL_1 (2-((E......
Highly efficient nickel/phosphine catalyzed cross-couplings of diarylborinic acids with aryl tosylat
4-Methoxy-4′-methylbiphenyl(3aa) [1] MeO White solid(0.324 g, 82% from aryl tosylate, 0.356 g, 90% from aryl sulfamate)......
Synthesis,Structure,and Luminescent Property of a 3-D Zinc Complex {[Zn_8~(II)(4-APha)_8(CH_3COO)_8]
The title complex [ZnⅡ8(4-APha)8(CH3COO)8(CH3CH2OH)2]n(1, 4-APha = 4-aminophenylhydroxamic acid) has been prepared unde......
Synthesis and Crystal Structures of Two Di-Cu(Ⅱ) Complexes Based on an Asymmetric Dinucleating Ligan
Two new dicopper(II) complexes [Cu2L(OAc)2](ClO4)·H2O(1) and [Cu2L(BPP)2]-(ClO4)(2) using an asymmetric dinucleating li......
Synthesis and Characterization of a Manganese(Ⅱ) Coordination Compound with Two-dimensional Layer St
A new complex {[Mn2(IP)2(1,4-bdc)2]·H2O}n(1)(IP = 1H-imidazo[4,5-f][1,10]-phenanthroline, 1,4-H2 bdc = 1,4-benzendicarb......
Colorimetric detection of glucose using a boronic acid derivative receptor attached to unmodified Au
A simple, cheap and non-enzymatic colorimetric strategy for glucose detection has been designed based on the interaction......
3-(Diphenylphosphino)propanoic acid: An efficient ligand for the Cu-catalyzed N-arylation of imidazo
3-(Diphenylphosphino)propanoic acid(L2) has proved to be an efficient ligand for the copper-catalyzed C–N coupling reac......
A new dimeric compound, [Zn(bpdc)(L)]2·4H2O(1, L = 11-fluoro-dipyrido[3,2-a:2’,3’-c]phenazine and bpdc = 1,1’-biphen......
Synthesis and Characterization of a Two-dimensional Cadmium(Ⅱ) Metal Organic Framework with Fes Topo
A new Cd(Ⅱ) coordination polymer, {[Cd(Hnbta)(L)]·H2O}n(L = 1,4-bis(5,6-dimethylbenzimidazol-1-yl)butane), H3nbta= 5-n......
Synthesis, Structure and Electrochemical Property of a New 3D Ag(I) Coordination Polymer Constructed
A new 3D Ag(I) coordination polymer, [Ag8(btc)2(bpp)2]n(1, H4btc = biphenyl- 2,2ˊ,4,4ˊ-tetracarboxylic acid, bpp = 1,2......
Promotional effects of cerium doping and NO_x on the catalytic soot combustion over MnMgAlO hydrotal
A series of MnMgAlO samples with different amounts of Ce doping were facilely prepared using coprecipitation method and ......
Synthesis and spectral characterization of lanthanide complexes with 1,2-diphenyl-4-butyl-3,5-pyrazo
The complexes of rare earth elements with 1,2-diphenyl-4-butyl-3,5-Pyrazolidinedione (PBH, phenylbutazone) were synthesi......
A New One-dimensional Lanthanum Thioantimonate(Ⅴ) with Bidentate Ethylenediamine and Tetradentate Tr
A new inorganic-organic hybrid lanthanum thioantimonate(V) with bidentate and tetradentate mixed amino ligands, namely L......
The reaction of bis(1,2,4-triazolyl-4-yl) (btr) and MnClO4·6H2O gave rise to a Mn(Ⅱ) complex comprised of unprecedente......
A metal-organic coordination polymer [Cd2(cbba)4(bix)2] n·nH2O (Hcbba=2-(4′-chlorine-benzoyl)-benzoic acid, bix=1,4-bi......
SYNTHESIS AND MAGNETIC PROPERTIES OF COMPLEXES OF A CONJUGATED HYPERBRANCHED POLYMER CONTAINING BITH
A novel conjugated hyperbranched polymer containing bithiazole rings(PBTADB) was synthesized by polycondensation of 1,3,......
A Novel Three-dimensional Ni Coordination Polymer Based on Flexible Di-carboxylate Ligand and 4,4′-P
A novel Ni(II) coordination polymer [Ni(dtba)(4,4′-bpy)] (1, H2dtba = 2,2′-dithio- bisbenzoic acid, 4,4′-bpy = 4,4′-......
Three novel rare earth complexes [N(CH 3) 4 ][Ln(NF) 4 ]·6H 2 O(Ln=Nd(III)(1),Sm(III)(2),Ho(III)(3)) were synthesized u......
Two Interpenetrated Dia-type Coordination Polymers Constructed from Mixed Dicarboxylate and Bis(imid
Two novel interpenetrating diamond frameworks,namely [Cd(mal)(bix)]n(1) and {[Zn(sub)(bib)]n·H2O}n(2)(H2mal=maleic acid......
Hydrothermal synthesis, structures and properties of metal phosphonates based on m-xylylenediphospho
In this work, a series of new metal phosphonates were hydrothermally synthesized and structurally characterized based on......
Synthesis,Crystal Structure and Properties of Barium Coordination Compound Based on 1,3,5-Benzenetri
A new coordination polymer [Ba3(btc)2(H2O)8]·2H2O(1, H3 btc = 1,3,5-benzenetricarboxylic acid) has been synthesized and......
A new 1D Cd(II) coordination polymer, [Cd(H2biim)2(SO4)]n·3n H2O(1, H2 biim = 2,2’-H2biimidazole), has been hydrotherm......
A new 3D heterometallic coordination polymer, namely [K2Pr2(C2O4)4·H2O]n(1), has been successfully synthesized under hy......
Syntheses and Crystal Structures of Two Coordination Polymers of Cobalt and Cadmium Assembled by 4,4
Two new metal-organic coordination polymers [Co0.5(Heoba)(bib)0.5]2n(1) and [Cd(eoba)(phen)]n(2)(H2eoba = 4,4-(ethane-1,......
Mechanism and microstructure of Eu(Ⅲ) interaction with γ-MnOOH by a combination of batch and high re
In this paper,the macroscopic interaction method and high resolution EXAFS technique with a bent crystal analyzer were c......
Synthesis,Crystal Structure and Properties of a 3-Fold Interpenetrating 3D Cd(Ⅱ) Complex Derived fro
A new Cd~Ⅱ coordination complex,namely [Cd(iba)_2]_n(1),was prepared by the hydrothermal reaction of Cd(NO_3)_2·4H_2O ......
Synthesis,Structure,and Surface Photo-electric Properties of a New Zn(Ⅱ) Coordination Complex Constr
A new binuclear Zn~Ⅱ coordination complex,Zn_2(bta)(phen)_2(Cl)_3(1,Hbta = 2-(1Hbenzotriazol-1-yl)acetic acid and phen ......
Synthesis, Structure and Photoluminescence of a New Pb(Ⅱ) Coordination Polymer [Pb(1, 4-chdc)(L)]_n·
A new Pb(Ⅱ) coordination polymer, [Pb(1,4-chdc)(L)]_n·nH_2O(1), was synthesized under hydrothermal condition(1,4-H2 ch......
Magnetic Properties in Mononuclear Gadolinium(Ⅲ) and Terbium(Ⅲ) Complexes Based on Ethoxylphenylsubs
Two new lanthanide complexes with ethoxybenzene-substituted nitronyl nitroxide radical(NIT-C_8H_9O) and hexafluoroacetyl......
A new mixed metal iodate, namely Ag Cu(IO_3)_3, has been prepared using hydrothermal method. Ag Cu(IO_3)_3 crystallizes ......
Synthesis,Crystal Structure,and Luminescence of a 1D Chain Cd(Ⅱ) Polymerwith 3,3?,5,5?-Benzene-1,3-b
A new Cd(Ⅱ) coordination polymer, [Cd(H_2btb)(bpy)]_n(1, H_4btb = 3,3?,5,5?-benzene-1,3-biyl-tetrabenzoic acid, bpy = 2......