Mechanistic insight into the selective cyclization of arylnitrones to indolines via Rh(Ⅲ)catalyst:a

来源 :第十三届全国量子化学会议 | 被引量 : 0次 | 上传用户:ldjlovell
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  Transition-metal catalyzed C-H bond functionalization have emerged as a powerful synthetic method and been extensively reported.[1] Recently,Chatani et al [2]reported the rhodium-catalyzed reaction of t-butyl aryl 2-pyridyl ether(R)with bis(pinacolato)diboron(B2(pin)2)leading to the arylboronic acid derivatives via activation of the C(aryl)-O bonds.
其他文献
We present a systematic theoretical investigation of visible light-mediated homogeneous gold-catalyzed 1,2-difunctionlization of alkynes using density functional theory.
Stable carbocations such as tritylium ions have been widely explored as organic Lewis acids catalysts and reagents in organic synthesis.[1] However,to achieve asymmetric carbocation catalysis remains
The fission of singlet to triplet in acene has been expected to elevate the quantum efficiency of organic solar cells.However,controversies also exist on the energies of singlet and triplet states in
To illustrate the formation mechanism of normal and abnormal N-heterocyclic carbene-carbon dioxide adducts(NHC-CO2 and aNHC-CO2),we implement DFT calculations on the reactions of imidazolium-based ion
Density functional theory calculations were performed on Rh(Ⅲ)-catalyzed synthesis of indolines from arylnitrones and alkynes,which provides an efficient method integrating C–H activation with O-atom
Recently,Liu et al(Chem.Sci.2015,6,2297-2301.)reported a green and novel approach to synthesizing α-hydroxy ketones from the hydration of propargylic alcohols in several ionic liquids under atmospheri
Understanding the catalytic cleavage mechanism of the β–O–4 bond of lignin is of crucial importance for developing efficient depolymerization strategies of lignin.
Boron-containing heterocyclic clusters possess unique bonding characteristics.
In this study,hybrid density functional theory[1] is used to study oxidation of methane to methanol mediated by the [CuⅡCuⅡ(μ-O)2CuⅢ(7-N-Etppz)]1+complex.[2] Based on the calculated free-energy profil
Allylmetal species are important intermediates in organic synthesis.[1] Recently, Stamatis E. Korkis and co-workers[2] first reported allyl-to-allyl 1,4-Rh(Ⅲ) migration in the oxidative C-H allylation