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Ultralow dielectric-constant (κ) porous SiCO(H) films were prepared using C7H18O3Si (MTES) and C 10H16 (LIMO) precursors by plasma enhanced chemical vapor deposition (PECVD) and post-deposition annealing.This paper well demonstrated the effect of LIMO/MTES flow rate ratio on the performance of the SiCO(H) film.When the flow rate ratio was 1.5, the SiCO(H) films exhibited the lowest κ value of 2.2 and extremely low leakage current density of 5.3×l0-9A/cm2 at 1 MV/cm, Young's modulus of 4.23 GPa, and hardness of 0.55 GPa after annealing at 420℃ for 4 h in N2 ambient.