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分别采用以乙酰乙酸乙酯、三聚甲醛为原料和以壬二酸为原料的两条不同合成路线,合成出具有生物活性的3-甲基环己-2-烯酮和(±)-3-甲基环己-2-烯醇。其结构均经过IR1、HNMR1、3CNMR和MS谱图的验证。对两条不同合成路线进行比较,讨论了影响合成的因素。并用合成化合物对纵坑切梢小蠹进行生物活性测试。
Two biosynthetic routes of 3-methylcyclohex-2-enone and (±) -3 were synthesized using ethyl acetoacetate, trioxane as raw materials and azelaic acid as starting materials respectively. Methylcyclohex-2-enol. Its structure has been verified by IR1, HNMR1, 3CNMR and MS spectra. The two different synthetic routes were compared and the factors affecting the synthesis were discussed. The bioactivity of the compounds was tested by using the synthesized compounds.