The protecting-group-free synthesis of versatile glycopolymers accelerated by microwave irradiation in an emulsion system is presented herein.Copper-catalyzed azide-alkyne cycloaddition (CuAAC) was employed to prepare a wide range of glycosylated hydrophilic monomers,and a series of glycopolymers were fabricated via ring-opening metathesis polymerization (ROMP).