介绍并比较了胶束催化的两种理论模型 :假相离子交换 ( Pseudophase ion exchange,PIE)模型和 Poisson- Boltzmann方程 ( PBE)模型。 PIE模型通过计算各反应物在两相间的分配 ,成功地解释了总一级反应速率常数 k1随各参数的变化和胶束表面的反离子竞争结合。 PBE模型完善了 PIE模型 ,考虑了胶束的尺寸和分布 ,胶束与离子间的静电作用和其它特殊作用 ,可解释一些 PIE模型无法解释的实验现象。 Two theoretical models of micellar catalysis are introduced and compared: Pseudophase ion exchange (PIE) model and Poisson-Boltzmann equation (PBE) model. PIE model by calculating the distribution of the reactants in the two-phase, successfully explained the total first-order reaction rate constant k1 with the changes of various parameters and the micellar surface competitive counterions. The PBE model improves the PIE model, considers the size and distribution of micelles, the electrostatic interactions between micelles and ions, and other special effects that explain some of the experimental phenomena that PIE models can not explain.