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系统研究了热处理对Ti-5Al-1.5Nd,Ti-5Al-4Sn-1.5Nd(质量分数,%)两种钛合金中析出相长大规律的影响.结果表明,含Nd的钛合金的快凝态基体中分布着大量近球状的析出相,并沿晶体的晶界、亚晶界、位错线等处呈串状析出.在650-800℃温度范围内经不同时间热处理后,析出相逐渐聚集长大,但长大速度都很慢.Ti-5Al-1.5Nd合金中析出相为立方的Nd_2O_3,其长大激活能为117kJ/mol.加入Sn后,析出相的分布更加弥散,析出相中Nd和Sn的平均原子比为1.37:1,经衍射花样的标定,判定为正交的Nd_5Sn_4,其长大速度更慢,长大激活能为170kJ/mol.
The effects of heat treatment on the precipitation regularity of Ti-5Al-1.5Nd, Ti-5Al-4Sn-1.5Nd (mass fraction,%) titanium alloys were systematically investigated. The results show that a large number of near-spherical precipitates are present in the rapidly solidified matrix of the Nd-containing titanium alloy, and are precipitated in series along grain boundaries, subgrain boundaries and dislocation lines. In the 650-800 ℃ temperature range after heat treatment at different times, the precipitated phase gradually gathered to grow, but the growth rate is very slow. Ti-5Al-1.5Nd alloy precipitation phase cubic Nd_2O_3, the activation energy of its growth was 117kJ / mol. After Sn is added, the distribution of precipitated phase is more dispersed. The average atomic ratio of Nd and Sn in the precipitated phase is 1.37: 1. After the diffraction pattern is calibrated, Nd_5Sn_4, which is orthogonally determined, grows more slowly and grows The activation energy is 170 kJ / mol.